Effect of Potential Step (dE) of Potential Signal to the Splitting Net-Peak Phenomena of an EC’EC’ Mechanism in Protein-Film Square-Wave Voltammetry

Gulaboski, Rubin (2024) Effect of Potential Step (dE) of Potential Signal to the Splitting Net-Peak Phenomena of an EC’EC’ Mechanism in Protein-Film Square-Wave Voltammetry. [Experiment] (Unpublished)

Text (MATHCAD Simulation Protocol) Potential Step (dE) effect to Protein-Film voltammetry of an EC'EC' mechanism-Gulaboski 08 04 2024.pdf - Draft Version Download (764kB)

Abstract

As electrochemical transformation of various redox enzymes often takes place in two consecutive steps, it is quite difficult to modeling such systems under voltammetric conditions. In couple of our previous works, we presented the voltammetric results of a surface EC’EC’ mechanism in square-wave voltammetry, considering both electron transfer steps to be very fast and happening at potentials separated more than 200 mV. The effect of the potential step (dE) in such scenario is presented in this work that can help in better understanding of this complex electrode mechanism, in order to get access to kinetic and thermodynamic parameters related to both electron transfer steps.

Item Type:	Experiment
Subjects:	Natural sciences > Chemical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	08 Apr 2024 10:35
Last Modified:	08 Apr 2024 10:35
URI:	https://eprints.ugd.edu.mk/id/eprint/33990

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