Theoretical Aspects of Diffusional Two Step Electrochemical Mechanism Associated with Regenerative Reaction to First Electrochemical Step and Follow Up Reversible Chemical Reaction Linked to the Product of Second Electrochemical Step

Gulaboski, Rubin (2023) Theoretical Aspects of Diffusional Two Step Electrochemical Mechanism Associated with Regenerative Reaction to First Electrochemical Step and Follow Up Reversible Chemical Reaction Linked to the Product of Second Electrochemical Step. [Experiment] (Unpublished)

Text (MATHCAD FIle for Diffusional EC'ECrev Mechanism) EC'ECrev Mechanism in SWV-Theory 2023.pdf - Draft Version Download (487kB)

Abstract

The entire MATHCAD Simulation protocol is presented for the diffusional two-step electrochemical mechanism, in which irreversible regenerative chemical reaction is associated to the first electrochemical step, while a reversible follow up chemical reaction is linked to the second electron transfer step. While plenty of simulated voltammograms are provided, hints are given on how to perform relevant simulations of this complex electrochemical model. The EC'ECrev mechanism is closely linked to the redox chemistry of many water soluble redox proteins (cytochromes, for example) and physiologically active systems (Vitamin C).

Item Type:	Experiment
Subjects:	Natural sciences > Chemical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	15 Sep 2023 09:27
Last Modified:	15 Sep 2023 09:27
URI:	https://eprints.ugd.edu.mk/id/eprint/32199

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