Janeva, Milkica and Kokoskarova, Pavlinka and Gulaboski, Rubin (2021) Theory of Square-wave Voltammetry of Two-step Surface Electrode Mechanisms Associated with Chemical Equilibria. . (Unpublished)
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Theory of TWO-STEPS Electrode Mechanisms-Associated with Chemical Reactions 2021-1.pdf Download (1MB) | Preview |
Abstract
Two-step electrode mechanisms that are associated with chemical equilibria are considered theoretically under conditions of square-wave voltammetry. The mechanisms designated as "surface EE", "surface ECE", "surface EECrev" and "surface EECatalytic" mechanisms are often encountered in experimental chemistry of many drugs and redox enzymes containing ions of transient metals as co-factors, or quinone-moieties, as well. We present large set of representative results that reveal specific features met at all considered mechanisms. We also propose set of simple methodologies to get access to kinetic and thermodynamic parameters relevant to electron transfer step, and to associated chemical reactions, as well. The work is of outmost importance to understand many aspects of enzyme-substrate interactions, but also the nature of drug-drug interactions of lipophilic and hydrophilic drugs.
| Item Type: | Teaching Resource |
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| Subjects: | Medical and Health Sciences > Basic medicine Natural sciences > Chemical sciences Natural sciences > Physical sciences |
| Divisions: | Faculty of Medical Science |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 22 Feb 2021 12:04 |
| Last Modified: | 22 Feb 2021 12:04 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/27855 |
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