Nernstian Behavior of Simple Diffusional Electrode Transformation in Square-Wave Voltammetry

Reversible Electrode Transformation, with mass transfer occurring via diffusion, described with the reaction scheme (I) is simulated in conditions of square-wave voltammetry;
Ox(dissolved) + ne = Red(dissolved)
Alongside the parameters affecting the features of dimensionless square-wave voltammograms of simple diffusional electrode reaction following Nernst reversible behavior, we also present set of equations to evaluate real peak currents. Methodology presented is important to mechanistic purposes, but also to get access to the rate of diffusion.