Effect of the Frequency to the Features of a Diffusional EC’EC’ Mechanism in Square-Wave Voltammetry

Gulaboski, Rubin (2024) Effect of the Frequency to the Features of a Diffusional EC’EC’ Mechanism in Square-Wave Voltammetry. [Experiment] (Unpublished)

Text (MATHCAD Simulation Protocol) 1-Frequency Effect to the Diffusional EC'EC' Mechanism in SWV-MATHCAD-Gulaboski-April 23 2024.pdf - Draft Version Download (806kB)

Abstract

As two-step consecutive electron transfer mechanisms are common to the electrochemical transformation of many water-soluble redox proteins and enzymes under physiological conditions, it is a real challenge to model such systems when two regenerative steps are coupled to both electron transfer steps. In this work we show how the frequency of the square-wave potential signal affects the features of both voltammetric peaks. This scenario can be used to recognize such a complex mechanism, especially when both electron transfer step occur at same potential.

Item Type:	Experiment
Subjects:	Natural sciences > Chemical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	21 May 2024 12:26
Last Modified:	21 May 2024 12:26
URI:	https://eprints.ugd.edu.mk/id/eprint/34045

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