Effect of Kinetics of Electron Transfer to Splitting Phenomenon of a Surface EC’EC’ Mechanism Calculated at Moderate Rate of Regenerative Reactions in Square-wave Voltammetry

Gulaboski, Rubin (2024) Effect of Kinetics of Electron Transfer to Splitting Phenomenon of a Surface EC’EC’ Mechanism Calculated at Moderate Rate of Regenerative Reactions in Square-wave Voltammetry. [Experiment] (Unpublished)

Text (MATHCAD Simulation Protocol) Effect of KInetics of Electron transfer to surface EC'EC; MEchanism in conditions of split net SWV peaks-Gulaboski 2024.pdf - Draft Version Download (687kB)

Abstract

The net SWV splitting phenomenon is unique feature for surface confined electrode mechanisms characterized with very fast rates of electron transfer step. Two s0-called surface electrode mechanism is a platform of electrochemical consideration of many lipophilic redox enzymes. Since many of these enzymes undergo electrochemical transformation in two consecutive electron transfer steps, while being regenerated by defined substrates, it was of outmost importance to develop a model of so-called EC’EC mechanism under conditions of protein-film voltammetry. In this work, for the first time the MATHCAD simulation platform is presented of surface EC’EC’ mechanism.

Item Type:	Experiment
Subjects:	Natural sciences > Chemical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	19 Mar 2024 09:09
Last Modified:	19 Mar 2024 09:09
URI:	https://eprints.ugd.edu.mk/id/eprint/33870

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