Practical Guidelines to Recognize Electrochemical Mechanisms with Coupled Chemical Reactions in Square-Wave Voltammetry

Gulaboski, Rubin (2023) Practical Guidelines to Recognize Electrochemical Mechanisms with Coupled Chemical Reactions in Square-Wave Voltammetry. [Experiment] (Unpublished)

Text (Guideline for Square-Wave Voltammetric Mechanisms) 1-Guidelines to Recognize Electrochemical Mechanisms with Coupled Chemical Reactions in Square.pdf - Draft Version Download (220kB)

Abstract

Although the square-wave voltammetry (SWV) is recognized as a leading member in the family of “Pulse” Voltammetric techniques, yet it is quite difficult for many experimentalists to recognize certain electrode mechanism simply from the features of obtained square-wave voltammograms. In this work, a series of theoretical square-wave voltammograms are presented, simulated for E, EC, CE and EC’ mechanisms. Voltammetric patterns presented in this work are calculated as a function of the chemical rate parameters, and they provide quite specific features that can be explored for identification of some one-step electrode mechanism coupled with defined chemical reaction. The voltammograms presented in this work can serve as a simple guideline for the students and for those with not enough knowledge in voltammetry.

Item Type:	Experiment
Subjects:	Natural sciences > Chemical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	07 Sep 2023 11:38
Last Modified:	07 Sep 2023 11:38
URI:	https://eprints.ugd.edu.mk/id/eprint/32179

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