Electrochemistry of Lipophilic Redox Enzymes Associated with a Reversible Follow‐up Chemical Reaction‐Theoretical Consideration in Cyclic Staircase Voltammetry

Gulaboski, Rubin (2022) Electrochemistry of Lipophilic Redox Enzymes Associated with a Reversible Follow‐up Chemical Reaction‐Theoretical Consideration in Cyclic Staircase Voltammetry. Electroanalysis, 34 (8). pp. 1-21. ISSN 1040-0397

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Abstract

Protein-film voltammetry (PFV) is established as an efficient methodology for studying the redox activity of lipophilic proteins and enzymes some 25 years ago. Yet it is still a challenge to understand specific behavior of these systems under different voltammetric conditions. In this work we apply cyclic staircase voltammetry to study theoretically the electrochemical properties of lipophilic redox enzymes, whose product of the electrochemical transformation at the working electrode is involved in a reversible chemical reaction. Attention is paid to understand how the kinetics of follow-up chemical reaction affects the features of theoretical staircase cyclo-voltammetric patterns of lipophilic redox enzymes.

Item Type:	Article
Impact Factor Value:	3.077
Subjects:	Medical and Health Sciences > Basic medicine Natural sciences > Chemical sciences Natural sciences > Physical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	23 Aug 2022 07:25
Last Modified:	23 Aug 2022 07:25
URI:	https://eprints.ugd.edu.mk/id/eprint/30093

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