Gulaboski, Rubin (2021) TWo-Step Protein-Film Voltammetry Coupled with Intermediate Reversible Chemical Step-MATHCAD Simulation File. [Dataset] (Unpublished)
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Protein Film Voltammetry of ECrevE mechanism with Reversible Chemical Step.pdf - Supplemental Material Download (518kB) |
Abstract
Two-step electrode mechanisms coupled with intermediate reversible chemical reaction between both electron transfer step are common for many redox proteins. Protonation/deprotonation, for example, is a chemical step that bridges multielectron transfer in many redox proteins such as cytochromes, redox enzymes with quinone-moieties in their structures, and also some redox proteins with transient metals. We give the readers entire working MATHCAD protocol to simulate the redox chemistry of such systems in square-wave voltammetry. In this work, we are also focused on redox proteins with inverted potentials, while we provide diagnostic criteria to recognize such systems in square-wave voltammetry.
| Item Type: | Dataset |
|---|---|
| Subjects: | Natural sciences > Biological sciences Natural sciences > Chemical sciences Natural sciences > Physical sciences |
| Divisions: | Faculty of Medical Science |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 25 Jun 2021 06:42 |
| Last Modified: | 25 Jun 2021 06:42 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/28232 |
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