Mirceski, Valentin and Gulaboski, Rubin (2020) Square-wave Voltammetry-Recent Bibliography from Macedonian Authors. [Dataset] (Unpublished)
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Abstract
Square-wave voltammetry (SWV) is recognized as a key electrochemical technique for getting
insight in important electrode mechanisms, but also in kinetics and thermodynamic aspects
of relevant biological and chemical systems []. It is ubiquitous technique that is widely
explored in physics, chemistry, pharmacy, medicine, and biology. From the features of squarewave voltammograms one gets relevant information about the charge-transfer, adsorption
and mass-transport phenomena taking place at the working electrode surface. Moreover, it
is a very suitable tool for analysing relevant aspects of chemical reactions that are coupled to
the electron transfer steps of electrode reactions []. Such electrochemical systems are quite
pertinent since they mimic important physiological processes []. The voltammetric theories
of such systems, based mainly on the Butler-Volmer formalism, reveal key mechanistic, kinetic
and thermodynamic insights about processes affecting the features of voltammetric outputs.
Estimation of the magnitude of standard rate constant of electron transfer step(s) ks
o
encompasses one of the most important applications of Square-wave voltammetry. The
correlation of ks
o with the difference in energy levels of atomic orbitals of working electrode
and molecular/ionic orbitals of analyzed substrates provides key information about kinetics
of many processes met in electrochemistry of various redox-active systems. For
electrochemical reactions that are associated with chemical reactions, by combining the
Butler-Volmer equation with modified Fick's laws we obtain implicit expressions that link the
magnitude of Faradaic current (I) with the applied potential (E), and with parameters related to the kinetics of relevant processes involved in given electrochemical mechanism. We present in this work recent bibliography about theoretical modelling in Square-wave
voltammetry of two Macedonian Authors-Valentin Mirceski and Rubin Gulaboski. It contains references that are relevant to various surface and diffusional mechanisms that are seen as models for many physiologically active systems.
| Item Type: | Dataset |
|---|---|
| Subjects: | Natural sciences > Chemical sciences Natural sciences > Physical sciences |
| Divisions: | Faculty of Medical Science |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 06 Oct 2020 10:11 |
| Last Modified: | 06 Oct 2020 10:11 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/26599 |
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