Mirceski, Valentin and Stojanov, Leon and Gulaboski, Rubin (2020) Double-sampled differential square-wave voltammetry-Supplementary Material to work published in J Electroanal Chem 872 (2020). [Dataset]
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Abstract
A differential form of square-wave voltammetry (SWV) is proposed based on a double sampling current protocol within the last quarter of the duration of each potential pulse. Differential forward (Id,f) and backward (Id,b) current components are well defined peaks with precisely accessible peak characteristics, which is not the case in conventional variant of the technique where most frequently one encounters asymmetric or sigmoid curves. The proposed methodology is theoretically tested with a simple quasi-reversible electrode reaction of a dissolved redox couple at a macroscopic planar electrode, as well as with the mechanism where the electrode reaction is coupled with a follow-up chemical reaction (i.e. ECr mechanism). Additional materials simulated for this work are given in this part of the published paper in J Electroanal Chem 872 (2020) 1-7
| Item Type: | Dataset |
|---|---|
| Subjects: | Natural sciences > Chemical sciences Natural sciences > Matematics Natural sciences > Physical sciences |
| Divisions: | Faculty of Medical Science |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 02 Oct 2020 07:46 |
| Last Modified: | 02 Oct 2020 07:46 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/24490 |
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