Gulaboski, Rubin and Mirceski, Valentin (2020) Protein-film voltammetry of surface Ox(ads) + ne = Red(ads) mechanism: Simulation procedure in Square-wave voltammetry-A MATHCAD file. [Dataset] (Unpublished)
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MATHCAD FILE of simple SURFACE Ox(ads) +ne = Red(ads) in SWV.pdf Download (1MB) | Preview |
Abstract
Surface reaction Ox(ads) + ne- = Red(ads), in which both participants are firmly adsorbed at the working electrode surface is considered as an adequate model for many redox enzymes analyzed in protein-film voltammetry. We give the readers entire working MATHCAD file to simulate this mechanism under conditions of square-wave voltammetry. The features of simulated voltammograms is function of number of exchanged electrons, electron transfer coefficient, potential step, square-wave amplitude, and on dimensionless parameter related to the kinetic of electron transfer lambda L, defined as L= ks/f, where ks is standard rate constant of electron transfer and ‘f’ is the SW frequency. Relevant thermodynamic and kinetic parameters of many lipophilic enzymes can be evaluated with this model, which can be of help for scientists working in protein-film voltammetry.
| Item Type: | Dataset |
|---|---|
| Subjects: | Natural sciences > Biological sciences Natural sciences > Chemical sciences Natural sciences > Computer and information sciences Natural sciences > Matematics Natural sciences > Physical sciences |
| Divisions: | Faculty of Medical Science |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 18 Mar 2020 09:01 |
| Last Modified: | 18 Mar 2020 09:01 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/23929 |
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