Mirceski, Valentin and Gulaboski, Rubin (2003) Two-step enzymatic reactions analyzed with protein film voltammetry-A theoretica model in square-wave voltammetry-MATHCAD simulation file. [Dataset]
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TWO-STEP SURFACE EE Mechanisam IN SWV PROTEIN FILM VOLTAMMETRY 2020.pdf Download (416kB) | Preview |
Abstract
Many lipophilic enzymes that contain quinone moieties or multivalent cations of W, V, Cr, Mo, Mn, Fe as redox active centers, exhibit electrochemical transformation in two successive steps. We provide the readers a full MATHCAD file with all relevant simulation parameters that can be used free for everyone to simulate this mechanism under conditions of square-wave voltammetry. The simulated voltammetric patterns are functions of kinetic parameters relevant to the first and the second electron transfer step, but also on the potential separation between both electrode steps. Moreover, in case of equal energy of transformation, both processes are portrayed in a single oxidation-reduction voltammetric pattern. This is a challenging situation that can be successfully resolved via coupling the second electron transfer step by follow-up chemical reaction.
| Item Type: | Dataset |
|---|---|
| Subjects: | Natural sciences > Chemical sciences Natural sciences > Matematics Natural sciences > Physical sciences |
| Divisions: | Faculty of Medical Science |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 24 Feb 2020 11:05 |
| Last Modified: | 24 Feb 2020 11:05 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/23856 |
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