Kokoskarova, Pavlinka and Maksimova, Viktorija and Janeva, Milkica and Gulaboski, Rubin (2019) Supplementary Material related to paper: Protein‐film Voltammetry of Two‐step Electrode Enzymatic Reactions Coupled with an Irreversible Chemical Reaction of a Final Product – A Theoretical Study in Square‐wave Voltammetry (Electroanalysis April 2019. [Dataset]
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Supplementary Material for surface EECirr-MATHCAD FIle-April 2019.pdf Download (284kB) | Preview |
Abstract
We provide the readers a full MATHCAD File for simulating the surface EECirr mechanism under conditions of square-wave voltammetry. Everyone can use the stuff described in this file in order to make own simulations on reported protein-film mechanism. Redox mechanism we consider is one in which a consecutive two‐step electrode transformation occurs, and the product generated in the second electrochemical step at the electrode surface is coupled to a follow‐up irreversible chemical reaction, is theoretically considered under conditions of square‐wave voltammetry. The electrochemical description of considered systems is a “surface EECirr mechanism”. We point out several simple features that allow kinetic characterization of studied mechanism from time‐independent experiments at constant scan rate. Kinetics of interactions of many important enzyme-substrate systems can be studied with help of this mechanism.
| Item Type: | Dataset |
|---|---|
| Subjects: | Natural sciences > Chemical sciences Natural sciences > Matematics Natural sciences > Physical sciences |
| Divisions: | Faculty of Medical Science |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 20 Nov 2019 11:02 |
| Last Modified: | 20 Nov 2019 11:04 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/22890 |
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