Janeva, Milkica and Kokoskarova, Pavlinka and Maksimova, Viktorija and Gulaboski, Rubin (2019) Supplementary material to paper: Square‐wave Voltammetry of Two‐step Surface Electrode Mechanisms Coupled with Chemical Reactions – A Theoretical Overview (published in Electroanalysis August 2019). [Dataset]
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SUPPLEMENTARY MATERIAL to paper Two Step Electrode mechanisms in SWV 2019.pdf Download (250kB) | Preview |
Abstract
We give in this work the entire MATHCAD file for the two-step surface EECrev mechanism simulated under conditions of square-wave voltammetry. Square‐wave voltammetry (SWV) of so‐called “surface redox reactions” is seen as a simple and efficient tool to quantify large number of drugs, physiologically active substances and other important chemicals. In the referred work, we focus on theoretical SWV features of four complex surface electrode mechanisms, in which the electron exchange between the working electrode and the studied redox substrate takes place in two successive steps. While we present large number of calculated square‐wave voltammograms, we give hints to recognize particular two‐step surface mechanism, but also to distinguish it from other similar mechanisms. We present plenty of relevant aspects of surface two‐step surface EE, two‐step surface ECE and surface catalytic EEC’ mechanisms. Moreover, we present for the first time a series of theoretical results related to two‐step surface EECrev mechanism (i. e. two‐step surface reaction coupled to follow‐up reversible chemical step). Everyone can use this file for free in order to make simulations on referred mechanism.
| Item Type: | Dataset |
|---|---|
| Subjects: | Natural sciences > Chemical sciences Natural sciences > Matematics |
| Divisions: | Faculty of Medical Science |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 20 Nov 2019 11:29 |
| Last Modified: | 20 Nov 2019 11:29 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/22889 |
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