Gulaboski, Rubin (2024) Effect of equilibrium constant of chemical reaction to the features of square-wave voltammograms of a diffusional “CrevErev” mechanism featuring preceding homogeneous chemical step. [Experiment] (Unpublished)
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Text (MATHCAD Simulation File of CE Mechanism in Square-wave voltammetry showing the effect of Keq at high rates of preceding chemical step)
1-Effect of Keq in CE mechanism MATHCAD Protocol in cyclic voltammetry sept 2024.pdf - Draft Version Download (726kB) |
Abstract
The electrochemical diffusional mechanism featuring reversible homogeneous chemical reaction (diffusional :”CrevErev” mechanism) is solved theoretically under conditions of square-wave voltammetry. In this file, a MATHCAD simulation protocol of this important electrochemical mechanism is presented, while highlighting the effect of equilibrium constant of the chemical step to the features of all current components of simulated Square-wave voltammograms. Method for the determination of equilibrium constant (Keq) is proposed. MATHCAD file provided is free and ready to use.
| Item Type: | Experiment |
|---|---|
| Subjects: | Natural sciences > Chemical sciences |
| Divisions: | Faculty of Medical Science |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 17 Sep 2024 08:33 |
| Last Modified: | 17 Sep 2024 08:33 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/34635 |
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