Effect of the chemical reaction rate to the features of square-wave voltammograms of a “CrevErev” mechanism

Gulaboski, Rubin (2024) Effect of the chemical reaction rate to the features of square-wave voltammograms of a “CrevErev” mechanism. [Experiment] (Unpublished)

Text (MATHCAD SIMULATION Protocol of a Diffusional CrevErev mechanism in Square-wave voltammetry) CrevErev diffusional mechanism MATHCAD Protocol in SWV sept 2024 Gulaboski-Effect of chemical rate.pdf - Draft Version Download (721kB)

Abstract

The electrochemical diffusional mechanism coupled with reversible preceding homogeneous chemical reaction (CrevErev mechanism) is considered theoretically under condition of square-wave voltammetry. In this experimental data set, we present a MATHCAD simulation protocol of this important electrochemical mechanism. It is of outmost importance to understand how the chemical rate affects the features of simulated voltammetric patterns for different magnitudes of equilibrium constant of chemical step (Keq). MATHCAD file provided is free and ready to use.

Item Type:	Experiment
Subjects:	Natural sciences > Chemical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	02 Sep 2024 10:39
Last Modified:	02 Sep 2024 10:39
URI:	https://eprints.ugd.edu.mk/id/eprint/34591

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