Redox Systems with Inverted Potentials-MATHCAD Simulation Protocol for Resolving Overlapped Voltammograms with Inverted Potentials in Square-Wave Voltammetry

Gulaboski, Rubin and Mirceski, Valentin (2021) Redox Systems with Inverted Potentials-MATHCAD Simulation Protocol for Resolving Overlapped Voltammograms with Inverted Potentials in Square-Wave Voltammetry. [Dataset] (Unpublished)

Other (MATHCAD File) Redox Systems with Inverted Potentials MATHCAD File EECrev mechanism 2021.pdf - Supplemental Material Download (531kB)

Abstract

Multielectron physiological systems with inverted redox potentials are very often in biochemistry. Many quinone-containing enzymes, polyphenols, thiol-containing proteins, might exhibit unusual features upon redox transformation portrayed in lower energy for the second than for the first electron transfer step. In this work, we give a detailed MATHCAD simulation file that can be explored to simulate various conditions of two-step redox mechanism coupled with follow-up reversible chemical reaction (diffusional EECrev mechanism). Readers can get benefit of this file to design a relevant methodology suitable for resolving two overlapped peaks in square-wave voltammetry by varying the rate of the chemical step only.

Item Type:	Dataset
Subjects:	Natural sciences > Biological sciences Natural sciences > Chemical sciences Natural sciences > Physical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	29 Jun 2021 09:39
Last Modified:	29 Jun 2021 09:39
URI:	https://eprints.ugd.edu.mk/id/eprint/28262

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