The synthesis and characterization of polydibromoacetylene

Leben, Stanko and Janevski, Aco and Sebenik, Anton and Osredkar, Uci (1992) The synthesis and characterization of polydibromoacetylene. Polymer Bulletin, 28 (3). pp. 287-292.

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Polydibromoacetylenes were synthesized under different polymerization conditions and with Al-Ti coordinative catalysts. For the characterization of the polymers and for the study of the correlation between polymerization conditions and properties of the polymers, 13C MAS NMR, ESR and UV spectroscopies were used. The electrical conductivity of the polymers was measured in dependence on temperature. The energy gap decreased with increased crystallinity. As compared to polyacetylene the conductivity of polydibromoacetylenes was lower, but the stability against oxygen was higher. The polydibromoacetylenes were thermal stabile up to 200°C.

Item Type: Article
Subjects: Engineering and Technology > Materials engineering
Engineering and Technology > Other engineering and technologies
Divisions: Faculty of Technology
Depositing User: Aco Janevski
Date Deposited: 15 Apr 2013 13:37
Last Modified: 15 Apr 2013 13:37

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