Effect of Square-Wave Amplitude to the Splitting Net-Peak Phenomena of a Surface EC’EC’ Mechanism in Square-Wave Voltammetry

Gulaboski, Rubin (2024) Effect of Square-Wave Amplitude to the Splitting Net-Peak Phenomena of a Surface EC’EC’ Mechanism in Square-Wave Voltammetry. [Dataset] (Unpublished)

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Abstract

While many redox enzymes undergo electrochemical transformation in two consecutive steps, there is always a need to make mathematical models for such systems under voltammetric conditions in order to get insight into their kinetics and thermodynamics. In this work, we present the voltammetric results of a surface EC’EC’ mechanism in square-wave voltammetry, considering both electron transfer steps to be very fast and happening at potentials separated more than 200 mV. The effect of the square-wave amplitude in such scenario reveals aspects that can lead not only to mechanistic revelations, but also provides mean for kinetic determinations.

Item Type:	Dataset
Subjects:	Natural sciences > Chemical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	01 Apr 2024 09:58
Last Modified:	01 Apr 2024 09:58
URI:	https://eprints.ugd.edu.mk/id/eprint/33955

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