Two Regenerative Chemical Reactions Associated to both Electron Transfer Steps of a Diffusional EE Mechanism-Theory of an EC’EC’ Mechanism in Square-Wave Voltammetry

Gulaboski, Rubin (2024) Two Regenerative Chemical Reactions Associated to both Electron Transfer Steps of a Diffusional EE Mechanism-Theory of an EC’EC’ Mechanism in Square-Wave Voltammetry. [Dataset] (Unpublished)

Text (MATHCAD FILE and Simulation Protocol) EC'EC' Diffusional Model in SWV 2024-Gulaboski.pdf - Draft Version Download (736kB)

Abstract

While many water-soluble redox enzymes often undergo an electrochemical redox transformation in two consecutive electron transfer steps, it is very common situation under physiological conditions to have two different regenerative steps associated to both electron transfer steps of the so-called diffusional EE Mechanism. In this work, for the first time the theory of an EC’EC’ mechanism is presented, while model is solved under conditions of square-wave voltammetry. By simulating this important electrochemical mechanism, one can get relevant set of data about kinetics and mechanism of interactions between important redox enzymes and various substrates.

Item Type:	Dataset
Subjects:	Natural sciences > Chemical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	15 Mar 2024 11:19
Last Modified:	15 Mar 2024 11:19
URI:	https://eprints.ugd.edu.mk/id/eprint/33866

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