Identification of Anthocyanins and Anthocyanin-Derivatives in Vranec Wines During Aging

Ivanova, Violeta and Nikolić, Dragan and Vojnoski, Borimir and Hermosín-Gutiérrez, Isidro (2023) Identification of Anthocyanins and Anthocyanin-Derivatives in Vranec Wines During Aging. Scientific paper-Agriconference 2022: 32nd Scientific-Expert Conference of Agriculture and Food Industry. pp. 232-241. ISSN 2195-271X

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Abstract

This study aimed to characterization of anthocyanins (3-monoglucosides, 3-acetylglucosides, and 3-coumaroylglucosides), pyranoanthocyanins and hydroxyphenyl-pyranoanthocyanins in Vranec wines during aging of three years. The HPLC-DAD–ESI-MSn technique was applied for identification of anthocyanins and derived stable pigments pyranoanthocyanins. All anthocyanins presented mass spectra characterized with two signals, molecular ion M+ and fragment ions [M-162]+, [M-204]+ and [M-308]+ resulting from elimination of glucose, acetylglucose and p-coumaroylglucose moieties, respectively. From the group of pyranoanthocyanins, A-type and B-type vitisins, as well as hydroxyphenyl-pyranoanthocyanins have been determined according to their molecular ions (M+) and characteristic fragments.

Item Type: Article
Subjects: Natural sciences > Chemical sciences
Agricultural Sciences > Other agricultural sciences
Divisions: Faculty of Agriculture
Depositing User: Violeta Ivanova Petropulos
Date Deposited: 21 Nov 2023 12:14
Last Modified: 21 Nov 2023 12:14
URI: https://eprints.ugd.edu.mk/id/eprint/32605

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