Gulaboski, Rubin (2023) Theory of Diffusional ECirrECat Mechanism in Square-Wave Voltammetry. [Experiment] (Unpublished)
![[thumbnail of MATHCAD Simulation FIle]](/style/images/fileicons/text.png) |
Text (MATHCAD Simulation FIle)
Theory of Diffusional ECirrECat Mechanism in Square-wave Voltammetry-Gulaboski 18 Sept 2023.pdf - Draft Version Download (599kB) |
Abstract
For the first time, the theory of two-step electrochemical mechanism, in which the product of second electrochemical step is produced via chemical transformation from the product of first electrochemical step, and additionally involved in a regenerative irreversible chemical step is solved under conditions of square-wave voltammetry. While the entire MATHCAD file to simulate voltammograms of the so-called “ECirrECat” mechanism is presented, hints are given that can bring experimentalists a step closer to recognize this mechanism. The elaborated mechanism is met in the redox chemistry of many water-soluble enzymes and proteins, such as cytochromes for example.
| Item Type: | Experiment |
|---|---|
| Subjects: | Natural sciences > Chemical sciences |
| Divisions: | Faculty of Medical Science |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 21 Sep 2023 08:32 |
| Last Modified: | 21 Sep 2023 08:32 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/32225 |
Actions (login required)
 |
View Item |