Square-wave Voltammetric Theory of Two-Step Surface Electrode Mechanism Associated with Intermediate Irreversible Regenerative Chemical Reaction-SWV of Surface ECatE mechanism

Gulaboski, Rubin (2021) Square-wave Voltammetric Theory of Two-Step Surface Electrode Mechanism Associated with Intermediate Irreversible Regenerative Chemical Reaction-SWV of Surface ECatE mechanism. [Dataset] (Unpublished)

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Abstract

For the first time, we present theoretical model of a two-step surface electrode mechanism, in which an irreversible regenerative chemical reaction is associated to the first electron transfer step. The abbreviation of this mechanism is "Surface ECatE mechanism". The model is solved under conditions of square-wave voltammetry (SWV). Model is relevant for many lipophilic redox enzymes, whose redox transformation takes place in two consecutive electron transfer steps. While we present several sets of specific voltammograms relevant to this mechanism, readers can explore the MATHCAD file for free to simulate different conditions at such systems. Experimental systems are found in many quinone-containing redox enzymes, such as FAD enzymes involved in the oxidative phosphorylation mechanism.

Item Type:	Dataset
Subjects:	Medical and Health Sciences > Basic medicine Natural sciences > Chemical sciences Natural sciences > Physical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	05 Apr 2021 07:08
Last Modified:	05 Apr 2021 07:08
URI:	https://eprints.ugd.edu.mk/id/eprint/27974

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