Theory of Square-wave Voltammetry of Diffusional Two-Step Mechanism Associated with Reversible Follow Up Chemical Step-SWV of Diffusional EECrev Mechanism

Gulaboski, Rubin (2021) Theory of Square-wave Voltammetry of Diffusional Two-Step Mechanism Associated with Reversible Follow Up Chemical Step-SWV of Diffusional EECrev Mechanism. [Dataset] (Unpublished)

Text SWV Theory of Diffusional EECrev mechanism April 2021 Gulaboski.pdf - Presentation Download (564kB)

Abstract

Theory of electrochemical behavior of many hydrophilic physiological systems, whose electrode transformation takes place in two consecutive steps, additionally complicated by the reversible follow up chemical reaction to the final redox product, is presented under conditions of square-wave voltammetry. In this MATHCAD file, we give entire simulation protocol for calculating square-wave voltammograms as function of potential of redox transformation, of standard rate constants of electron transfer of both electrode reactions, but also as a function of equilibrium constant and the rate of chemical follow up reaction. The model is relevant for many neurotransmitters (dopamine), quinone-like drugs and many hydrophilic redox enzymes, such as cytochrome C. Readers can get full benefit of the MATHCAD file that can be incorporated for free for everyone in order to perform simulations

Item Type:	Dataset
Subjects:	Natural sciences > Chemical sciences Natural sciences > Physical sciences
Divisions:	Faculty of Medical Science
Depositing User:	Rubin Gulaboski
Date Deposited:	05 Apr 2021 07:08
Last Modified:	05 Apr 2021 07:08
URI:	https://eprints.ugd.edu.mk/id/eprint/27973

Actions (login required)

View Item