Gulaboski, Rubin (2020) Cyclic Square-Wave Voltammetry of a Surface CE Electrode Mechanism (MATHCAD Simulation Protocol). [Dataset] (Unpublished)
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Abstract
Although the potential ramp of cyclic square wave voltammetry is defined more than 30 years ago, it has been only 5 years ago to explore this technique for characterizing the so-called surface-confined electrode reactions (M. Mann, L. Bottomley, Cyclic Square Wave Voltammetry of Surface-Confined Quasireversible Electron Transfer Reactions, Langmuir 31 (2015) 9511-9520). Since this technique unifies the features of both cyclic and square-wave voltammetry, it has been a real challenge to apply this technique for experimental verification of the redox features of many lipophilic enzymes and drugs that can be strongly adsorbed at the surface of working electrode. We present in this work a set of theoretical voltammograms calculated for a Surface CE mechanism of type
A(ads) ----> Ox(ads)
Ox(ads) + ne- = Red(ads)
We present the readers entire MATHCAD Simulation working file to simulate voltammograms of this mechanism under conditions of Cyclic Square-Wave Voltammetry.The simulated voltammograms, together with the criteria given in this file will enable experimentalists to assign the electrode reaction mechanism and accurately measure electrode reaction kinetics.
| Item Type: | Dataset |
|---|---|
| Subjects: | Natural sciences > Biological sciences Natural sciences > Chemical sciences Natural sciences > Physical sciences |
| Divisions: | Faculty of Medical Science |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 13 Aug 2020 07:24 |
| Last Modified: | 13 Aug 2020 07:24 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/24236 |
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