Three-phase Boundaries and Three-phase Electrodes-Fundamental Principles to Understand Ion Transfer between two Immiscible Solvents (in Electrochemical Dictionary, A. Bard, G. Inzelt, F. Scholz, eds.)

Gulaboski, Rubin (2020) Three-phase Boundaries and Three-phase Electrodes-Fundamental Principles to Understand Ion Transfer between two Immiscible Solvents (in Electrochemical Dictionary, A. Bard, G. Inzelt, F. Scholz, eds.). ISBN 978-3-642-29551-5.

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Abstract

Three-phase boundary plays crucial role in understanding processes of electron/ion transfer across conjoined phases that are in close contact. It is of crucial importance to understand that the principle of charge electroneutrality in each phase prompts transfer of electrons and/or ions across immiscible phases, when charge neutrality is disturbed in one of the phases. With the three-phase electrode system, invented by Scholz and Lovric in 2020, it is achievable to determine the thermodynamic quantity Gibbs energy of ion transfer that is related to the potential of given ionized system (drugs, ions, molecules, ….) to be transferred and partitioned between two liquid systems. These phenomena are of crucial importance in the design of drugs, and in the transfer of ionized drugs and small molecules/ions across biological membranes. Short presentation of the basic principles of this methodology are present in this chapter, which is a part of the Electrochemical Dictionary edited by A. Bard, G. Inzelt and F. Scholz in 2012.

Item Type: Teaching Resource
Subjects: Natural sciences > Chemical sciences
Natural sciences > Physical sciences
Divisions: Faculty of Medical Science
Depositing User: Rubin Gulaboski
Date Deposited: 09 Jul 2020 07:21
Last Modified: 09 Jul 2020 07:21
URI: https://eprints.ugd.edu.mk/id/eprint/24198

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