Scholz, Fritz and Gulaboski, Rubin and Caban, Karolina (2003) The determination of standard Gibbs energies of transfer of cations across the nitrobenzene|water interface using a three-phase electrode. Electrochemistry Communications, 5 (11). pp. 929-934. ISSN 13882481
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Abstract
A three-phase electrode consisting of a droplet of a nitrobenzene solution of iron(III) tetraphenyl porphyrine chloride (Fe(III)-
TPP-Cl) attached to a graphite electrode and immersed in an aqueous electrolyte solution was applied to determine the standard
Gibbs energies of transfer of cations between water and nitrobenzene. The reduction of Fe(III)-TPP-Cl prompts the transfer of the
cations from the aqueous to the organic phase. The system is chemically and electrochemically reversible.
| Item Type: | Article |
|---|---|
| Subjects: | Medical and Health Sciences > Basic medicine Natural sciences > Biological sciences Natural sciences > Chemical sciences Natural sciences > Matematics Natural sciences > Physical sciences |
| Divisions: | Faculty of Agriculture |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 31 Oct 2012 13:17 |
| Last Modified: | 31 Oct 2012 13:17 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/171 |
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