Gulaboski, Rubin and Riedl, Kai and Scholz, Fritz (2003) Standard Gibbs energies of transfer of halogenate and pseudohalogenate ions, halogen substituted acetates, and cycloalkyl carboxylate anions at the water|nitrobenzene interface. Physical Chemistry Chemical Physics, 5 (6). pp. 1284-1289. ISSN 14639076
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Abstract
The previously introduced three-phase electrode technique was used to determine the Gibbs energies of
transfer of ClO3
�, BrO3
�, IO3
�, IO4
�, OCN�, SeCN�, CN�, N3
�, halogen substituted acetate anions
Z3�nCHnCOO� (Z ¼ F,Cl,Br,I), and cycloalkyl carboxylate anions ((CH2)nCOO�, n ¼ 3,. . .,7) at the
water|nitrobenzene interface. Whereas the data for the small inorganic ions can easily be understood
in terms of ion-dipole interactions, the data of the organic ions need consideration of charge
delocalisation and its effect on the enthalpy and entropy of solvation.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ionizable drugs, ion transfer, liquid liquid interfacem drug design, voltammetry, lipophilicity, thermodynamics |
| Subjects: | Medical and Health Sciences > Basic medicine Natural sciences > Biological sciences Natural sciences > Chemical sciences Natural sciences > Physical sciences |
| Divisions: | Faculty of Agriculture |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 31 Oct 2012 13:16 |
| Last Modified: | 31 Oct 2012 13:16 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/164 |
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