Gulaboski, Rubin and Mirceski, Valentin and Bogeski, Ivan and Hoth, Markus (2012) Protein film voltammetry: electrochemical enzymatic spectroscopy. A review on recent progress. Journal of Solid State Electrochemistry, 16 (7). pp. 2315-2328. ISSN 1432-8488
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Abstract
This review is focused on the basic principles,
the main applications, and the theoretical models developed
for various redox mechanisms in protein film voltammetry,
with a special emphasis to square-wave voltammetry as a
working technique. Special attention is paid to the
thermodynamic and kinetic parameters of relevant enzymes
studied in the last decade at various modified electrodes,
and their use as a platform for the detection of reactive
oxygen species is also discussed. A set of recurrent
formulas for simulations of different redox mechanisms of
lipophilic enzymes is supplied together with representative
simulated voltammograms that illustrate the most relevant
voltammetric features of proteins studied under conditions
of square-wave voltammetry.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | protein-film voltammetry, square-wave voltammetry, mathematical modeling, kinetics of electron transfer, thermodynamics, lipophilic proteins, voltammetry, nanoparticles, biosensors |
| Subjects: | Medical and Health Sciences > Basic medicine Natural sciences > Biological sciences Natural sciences > Chemical sciences Natural sciences > Physical sciences |
| Divisions: | Faculty of Agriculture |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 31 Oct 2012 13:14 |
| Last Modified: | 05 Nov 2012 11:07 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/158 |
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