Scholz, Fritz and Gulaboski, Rubin and Mirceski, Valentin and Langer, Peter (2002) Quantification of the chiral recognition in electrochemically driven ion transfer across the interface water/chiral liquid. Electrochemistry Communications, 4 (8). pp. 659-662. ISSN 13882481
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Abstract
The electrochemically driven transfer of the chiral anions of D- and L-tryptophan across the interface water/chiral liquid (D- or Lmenthol)
is stereoselective, and it can be used to determine quantitatively the difference in Gibbs energies for the solvation of chiral
ions in chiral liquids. The ion transfer can be achieved in a three-phase arrangement where a droplet of the chiral liquid containing
decamethylferrocene as the electroactive redox probe is attached to a graphite electrode immersed in the aqueous solution containing
the chiral ions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | chiral amino acids, liquid-liquid interface, biomimetic membranes, ion transfer, standard Gibbs energy of io transfer, voltammetry |
| Subjects: | Natural sciences > Chemical sciences |
| Divisions: | Faculty of Agriculture |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 31 Oct 2012 13:10 |
| Last Modified: | 05 Nov 2012 11:10 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/138 |
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