Gulaboski, Rubin and Mirceski, Valentin and Komorsky-Lovrić, Šebojka and Lovrić, Milivoj (2004) Square-Wave Voltammetry of Cathodic Stripping Reactions. Diagnostic Criteria, Redox Kinetic Measurements, and Analytical Applications. Electroanalysis, 16 (10). pp. 832-842. ISSN 1040-0397
Preview |
Text
__ugd.edu.mk_private_UserFiles_rubin.gulaboski_Desktop_GULABOSKI-MY pdf PUBLICATIONS_Revial-Cathodic stripping reactions-electroanalysis 2004.pdf Download (200kB) | Preview |
Abstract
A comparative study of different types of cathodic stripping reactions under conditions of square-wave voltammetry is
presented. Cathodic stripping processes involving reactions of second order as well as reactions coupled by adsorption
of the reacting ligand are analyzed The inherent parameters, controlling the overall voltammetric behavior of each
cathodic stripping electrode reaction are derived. The criteria for qualitative distinguishing of each mechanism are
established as well as a methodology for redox kinetic measurements is proposed. The influence of the parameters of
the excitation signal on the properties of the voltammetric response is analyzed in order to find optimal conditions for
analytical application. The theoretical results are illustrated by the experiments with a series of uracil derivatives.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | uracils, cathodic stripping reactions, square-wave voltammetry, diagnostic criteria, kinetics of electron transfer, adsorption |
| Subjects: | Natural sciences > Chemical sciences |
| Divisions: | Faculty of Agriculture |
| Depositing User: | Rubin Gulaboski |
| Date Deposited: | 31 Oct 2012 10:26 |
| Last Modified: | 05 Nov 2012 11:08 |
| URI: | https://eprints.ugd.edu.mk/id/eprint/135 |
Actions (login required)
 |
View Item |