Diffusional "CE Mechanism" in Square Wave Voltammetry-MATHCAD Simulation Procedure

Gulaboski, Rubin (2020) Diffusional "CE Mechanism" in Square Wave Voltammetry-MATHCAD Simulation Procedure. [Dataset] (Unpublished)

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Abstract

Reaction of disproportionation or degradation of given compound „A” leads to generation of reactive species “Ox” that can undergo electron transfer at the working electrode surface. The mechnism known as Diffusional CE or simply CE Mechanism is considered under conditions of square-wave voltammetry. The reaction scheme of this mechanism met in many physiological systems is as follow A --> Ox(water) + ne- = Red(water) SW voltammetric patterns are function of the electron transfer parameter related to the electrode reaction, but they also depend on the kinetic and thermodynamic parameters related to the chemical step. The entire interplay of all parameters leads to very specific voltammograms, whose feature can reveal important kinetic and thermodynamic parameters relevant to the physiological systems of interest. Electrode transformation of many transient metal ion, drugs, enzymes, neurotransmitters, vitamins and metal-Ligand complexes follow this pathway.

Item Type: Dataset
Subjects: Medical and Health Sciences > Basic medicine
Natural sciences > Biological sciences
Natural sciences > Chemical sciences
Natural sciences > Computer and information sciences
Natural sciences > Matematics
Natural sciences > Physical sciences
Divisions: Faculty of Medical Science
Depositing User: Rubin Gulaboski
Date Deposited: 05 Apr 2020 20:33
Last Modified: 05 Apr 2020 20:33
URI: http://eprints.ugd.edu.mk/id/eprint/23965

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