Additional Supplementary Material (MATHCAD simulation Dataset) related to work published in Electroanalysis: Square‐wave Voltammetry of Two‐step Surface Electrode Mechanisms Coupled with Chemical Reactions – A Theoretical Overview

Janeva, Milkica and Kokoskarova, Pavlinka and Maksimova, Viktorija and Gulaboski, Rubin (2019) Additional Supplementary Material (MATHCAD simulation Dataset) related to work published in Electroanalysis: Square‐wave Voltammetry of Two‐step Surface Electrode Mechanisms Coupled with Chemical Reactions – A Theoretical Overview. [Dataset]

[img]
Preview
Text
MATHCAD FILE OF SURFACE EECrev Mechanisam IN SWV 2020-Additional Supplementary.pdf

Download (498Kb) | Preview
Official URL: http://dx.doi.org/10.1002/elan.201900416

Abstract

A challenging situation in all two-step surface mechanisms exists when both electron transfer steps take place at same potential. We provide in this work a data set for MATHCAD simulations of a surface protein-film voltammetry of EECreversible mechanism, with two electron transfer steps (EE) happening at same potential. With adjusting the rate of coupled chemical reaction, we can achieve successful separation of both electron transfer steps. This is because the rate of chemical step will displace the second electron transfer step towards more positive potential, while first process remains unaffected. The reported methodology in the MATHCAD file is the first approach in any voltammetric technique that enables recognition of a successive two-step mechanism when both electron transfers occur at same potential.

Item Type: Dataset
Subjects: Medical and Health Sciences > Basic medicine
Natural sciences > Chemical sciences
Natural sciences > Matematics
Natural sciences > Physical sciences
Divisions: Faculty of Medical Science
Depositing User: Rubin Gulaboski
Date Deposited: 17 Feb 2020 09:05
Last Modified: 17 Feb 2020 09:06
URI: http://eprints.ugd.edu.mk/id/eprint/23821

Actions (login required)

View Item View Item