Protein-film voltammetry of Successive two-step Electrode Mechanism coupled with irreversible regenerative reaction in Square-Wave Voltammetry-Theoretical Model with Simulation Parameters

Gulaboski, Rubin (2020) Protein-film voltammetry of Successive two-step Electrode Mechanism coupled with irreversible regenerative reaction in Square-Wave Voltammetry-Theoretical Model with Simulation Parameters. [Dataset] (Unpublished)

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THEORETICAL SIMULATION MODEL of protein film EEC' catalytic mechanism in SWV.pdf

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Abstract

Protein-film voltammetry is considered as an efficient electrochemical tool in analysis of electrochemical properties of many lipophilic enzymes. If we investigate the redox and chemical properties of an enzyme that have multivalent cations of Mo, W, V, Cr or quinone moiety as active centers, then the electrode transformation commonly takes place in two successive electron transfer steps. In a regenerative reaction is coupled to the last redox product of defined enzymatic reaction, we observe voltammetric patterns of so-called surface EEC' catalytic mechanism. We present in this work entire MATHCAD simulation file with all parameters relevant to the considered EEC' mechanism. This file can be used for free for everyone willing to simulate protein-film mechanisms in square-wave voltammetry. We provide also literature relevant to theoretical modeling in square-wave and cyclic voltammetry, as well many experimental achievements in this field.

Item Type: Dataset
Subjects: Medical and Health Sciences > Basic medicine
Natural sciences > Chemical sciences
Natural sciences > Matematics
Natural sciences > Physical sciences
Divisions: Faculty of Medical Science
Depositing User: Rubin Gulaboski
Date Deposited: 17 Feb 2020 09:05
Last Modified: 17 Feb 2020 09:05
URI: http://eprints.ugd.edu.mk/id/eprint/23820

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