Calculating Theoretical Square-wave voltammograms of a diffusional catalytic EC' mechanism-MATHCAD working file for performing simulations

Gulaboski, Rubin and Mirceski, Valentin (2019) Calculating Theoretical Square-wave voltammograms of a diffusional catalytic EC' mechanism-MATHCAD working file for performing simulations. [Dataset] (Unpublished)

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MATHCAD Working Sheet for SIMULATION OF DIFFUSIONAL EC' Mechanisam in SWV.pdf

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Abstract

Electrode reactions of many hydrophilic drugs and water-soluble enzymes can be coupled with so-called regenerative step. Under such conditions, a chemical reaction between the electrochemically generated product and a given (electro-inactive) substrate can led to regeneration of the initial reactant. This mechanism has quite specific features that can be used as diagnostic criteria for recognizing it. Moreover, the features of simulated voltammograms can give access to the Michaelis Menten constant of many enzyme-substrate reactions. We provide readers entire MATHCAD working sheet with all parameters affecting the theoretical voltammograms under conditions of square-wave voltammetry.

Item Type: Dataset
Subjects: Medical and Health Sciences > Basic medicine
Natural sciences > Biological sciences
Natural sciences > Chemical sciences
Natural sciences > Matematics
Natural sciences > Physical sciences
Divisions: Faculty of Medical Science
Depositing User: Rubin Gulaboski
Date Deposited: 24 Dec 2019 12:42
Last Modified: 24 Dec 2019 12:42
URI: http://eprints.ugd.edu.mk/id/eprint/23189

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