Supplementary Material related to paper: Protein‐film Voltammetry of Two‐step Electrode Enzymatic Reactions Coupled with an Irreversible Chemical Reaction of a Final Product – A Theoretical Study in Square‐wave Voltammetry (Electroanalysis April 2019

Kokoskarova, Pavlinka and Maksimova, Viktorija and Janeva, Milkica and Gulaboski, Rubin (2019) Supplementary Material related to paper: Protein‐film Voltammetry of Two‐step Electrode Enzymatic Reactions Coupled with an Irreversible Chemical Reaction of a Final Product – A Theoretical Study in Square‐wave Voltammetry (Electroanalysis April 2019. [Dataset]

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Supplementary Material for surface EECirr-MATHCAD FIle-April 2019.pdf

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Official URL: http://dx.doi.org/10.1002/elan.201900225

Abstract

We provide the readers a full MATHCAD File for simulating the surface EECirr mechanism under conditions of square-wave voltammetry. Everyone can use the stuff described in this file in order to make own simulations on reported protein-film mechanism. Redox mechanism we consider is one in which a consecutive two‐step electrode transformation occurs, and the product generated in the second electrochemical step at the electrode surface is coupled to a follow‐up irreversible chemical reaction, is theoretically considered under conditions of square‐wave voltammetry. The electrochemical description of considered systems is a “surface EECirr mechanism”. We point out several simple features that allow kinetic characterization of studied mechanism from time‐independent experiments at constant scan rate. Kinetics of interactions of many important enzyme-substrate systems can be studied with help of this mechanism.

Item Type: Dataset
Subjects: Natural sciences > Chemical sciences
Natural sciences > Matematics
Natural sciences > Physical sciences
Divisions: Faculty of Medical Science
Depositing User: Rubin Gulaboski
Date Deposited: 20 Nov 2019 11:02
Last Modified: 20 Nov 2019 11:04
URI: http://eprints.ugd.edu.mk/id/eprint/22890

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