Determination of Standard Gibbs Energies of Transfer of Organic Anions across the Water/Nitrobenzene Interface

Komorsky-Lovrić, Šebojka and Riedl, Kai and Gulaboski, Rubin and Mirceski, Valentin and Scholz, Fritz (2002) Determination of Standard Gibbs Energies of Transfer of Organic Anions across the Water/Nitrobenzene Interface. Langmuir, 18 (21). pp. 8000-8005. ISSN 0743-7463

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Official URL: http://dx.doi.org/10.1021/la020285o

Abstract

The oxidation of decamethylferrocene dissolved in a nitrobenzene droplet and attached to a graphite electrode that is immersed in an aqueous electrolyte solution provides the basis to determine the standard Gibbs energies of transfer of simple organic anions, such as those of aliphatic and aromatic mono- and dicarboxylic acids, and phenols. The data are rationalized on the basis of the constitution of the compounds.

Item Type: Article
Subjects: Medical and Health Sciences > Basic medicine
Natural sciences > Biological sciences
Natural sciences > Chemical sciences
Natural sciences > Physical sciences
Divisions: Faculty of Agriculture
Depositing User: Rubin Gulaboski
Date Deposited: 31 Oct 2012 13:15
Last Modified: 05 Nov 2012 12:39
URI: http://eprints.ugd.edu.mk/id/eprint/159

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