Protein film voltammetry: electrochemical enzymatic spectroscopy. A review on recent progress

Gulaboski, Rubin and Mirceski, Valentin and Bogeski, Ivan and Hoth, Markus (2012) Protein film voltammetry: electrochemical enzymatic spectroscopy. A review on recent progress. Journal of Solid State Electrochemistry, 16 (7). pp. 2315-2328. ISSN 1432-8488

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This review is focused on the basic principles, the main applications, and the theoretical models developed for various redox mechanisms in protein film voltammetry, with a special emphasis to square-wave voltammetry as a working technique. Special attention is paid to the thermodynamic and kinetic parameters of relevant enzymes studied in the last decade at various modified electrodes, and their use as a platform for the detection of reactive oxygen species is also discussed. A set of recurrent formulas for simulations of different redox mechanisms of lipophilic enzymes is supplied together with representative simulated voltammograms that illustrate the most relevant voltammetric features of proteins studied under conditions of square-wave voltammetry.

Item Type: Article
Uncontrolled Keywords: protein-film voltammetry, square-wave voltammetry, mathematical modeling, kinetics of electron transfer, thermodynamics, lipophilic proteins, voltammetry, nanoparticles, biosensors
Subjects: Medical and Health Sciences > Basic medicine
Natural sciences > Biological sciences
Natural sciences > Chemical sciences
Natural sciences > Physical sciences
Divisions: Faculty of Agriculture
Depositing User: Rubin Gulaboski
Date Deposited: 31 Oct 2012 13:14
Last Modified: 05 Nov 2012 11:07

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