Gibbs energies of transfer of chiral anions across the interface water|chiral organic solvent determined with the help of three-phase electrodes

Scholz, Fritz and Gulaboski, Rubin (2005) Gibbs energies of transfer of chiral anions across the interface water|chiral organic solvent determined with the help of three-phase electrodes. Faraday Discussions, 129. p. 169. ISSN 1359-6640

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Official URL: http://dx.doi.org/10.1039/b404539d

Abstract

For the first time the differences in free energies have been experimentally determined for the solvation of two enantiomeric ions in two enantiomeric solvents. Three-phase electrodes consisting of a droplet of a solution of decamethylferrocene in a chiral solvent (D- and L-2-octanol) attached to a graphite electrode and immersed in an aqueous solution containing chiral anions, allow the measurement of these data for the transfer of the enantiomeric ions across the water|chiral solvent interface. In all studied combinations the Gibbs energy to transfer an L-ion from water to the L-solvent was equal to the Gibbs energy of transfer of the D-ion from water to the D-solvent, and the same was found for the transfer of a L-ion from water to the D-solvent and for the D-ion from water to the L-solvent. In all cases, the combinations D-anion/D-solvent and L-anion/L-solvent have smaller standard Gibbs energies than the combinations D-anion/L-solvent and L-anion/ D-solvent. This can be explained by less favourable interactions between an anion and a solvent molecule in the latter cases.

Item Type: Article
Uncontrolled Keywords: ion transfer, chiral ions, voltammetry, liquid-liquid interface, biomimetic membranes, lipophilicitym standard Gibbs energy of ion transfer
Subjects: Natural sciences > Chemical sciences
Divisions: Faculty of Agriculture
Depositing User: Rubin Gulaboski
Date Deposited: 31 Oct 2012 13:10
Last Modified: 31 Oct 2012 13:10
URI: http://eprints.ugd.edu.mk/id/eprint/141

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