Biocomposites based on polylactic acid and their thermal behavior after recycling

Srebrenkoska, Vineta and Bogoeva-Gaceva, Gordana and Dimeski, Dimko (2014) Biocomposites based on polylactic acid and their thermal behavior after recycling. Macedonian Journal of Chemistry and Chemical Engineering. pp. 277-285. ISSN 1857-5552, e-ISSN 1857-5625


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In this study, rice-hull-filled polylactic acid (PLA) biocomposites were prepared through the addi-tion of 5 wt.% PLA-grafted-MA (CA) for the enhancement of adhesion between the polymer matrix and natural filler. The composites containing 30 wt.% rice hulls (RH) were prepared by compression molding, with particular attention given to the introduction of recycled PLA matrix, as well as to the possibility of the recycling and reuse of PLA/RH biocomposites. For all biocomposites, produced from neat polymer and RH and those produced after the recycling of PLA/RH composites, the mechanical and thermal prop-erties were analyzed and compared to those of a commonly used thermoplastic based-polymer, polypro-pylene (PP), containing the same reinforcement. Thermal stability of biocomposites based on recycled PLA matrix and of the new composites produced from recycled ones was practically unchanged. Intro-duction of the recycled PLA matrix into biocomposites resulted in decreased flexural modulus and strengths of about 50%. Utilization of the mixture obtained after the thermal-mechanical recycling of the whole biocomposite resulted in a composite with slightly increased flexural modulus and decreased flex-ural strength. The obtained results have shown that rice-hull-filled poly(lactic acid) biocomposites could be re-cycled and utilized for the production of new eco-materials with acceptable thermal and mechanical prop-erties. Namely, the results for flexural strength and modulus of the recycled biocomposite samples are comparable to those of conventional formaldehyde wood medium density fiberboards used as construc-tion elements for indoor applications.

Item Type: Article
Subjects: Engineering and Technology > Materials engineering
Divisions: Faculty of Technology
Depositing User: Vineta Srebrenkoska
Date Deposited: 22 Jan 2015 14:23
Last Modified: 22 Jan 2015 14:23

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