¹³C NMR analysis of polyvinyl chloride synthesisized with manganese ( III ) diacetylacetone rhodanide as initiators

Janevski, Aco and Sebenik, Anton and Petrov, Gjuro and Joseska, Nuska (1997) ¹³C NMR analysis of polyvinyl chloride synthesisized with manganese ( III ) diacetylacetone rhodanide as initiators. Bulletin of the Chemists and Technologists of Macedonia, 16 (2). pp. 139-148. ISSN 0350 – 0136

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Abstract

Configurational analysis was made of polyvinyl chloride(PVC) synthesized with manganese(III) diacetylacetonate rhodanide initiated polymerization. The Bernoullian probability for meso addition on the monomer units were found to be 0.434 from methine and 0.450,calculated from methylene 13C atoms. The results suggested radical polymerization mechanism.

Item Type: Article
Subjects: Natural sciences > Chemical sciences
Natural sciences > Physical sciences
Divisions: Faculty of Technology
Depositing User: Aco Janevski
Date Deposited: 26 Nov 2014 08:32
Last Modified: 26 Nov 2014 08:32
URI: http://eprints.ugd.edu.mk/id/eprint/11439

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